Zoning and exsolution in alkali feldspars from Laacher See volcano (Western Germany): constraints on temperature history prior to eruption     

Smruti?Sourav?RoutEmail authorView author&#;s OrcID profile  Gerhard?W?rner 《Contributions to Mineralogy and Petrology》2018,173(11):95

Compositional zoning and exsolution patterns of alkali feldspars in carbonatite-bearing cognate syenites from the 6.3 km³ (D.R.E) phonolitic Laacher See Tephra (LST) deposit in western Germany (12.9 ka) are reported. These rocks represent the cooler outer portion and crystal-rich products of a cooling magma reservoir at upper crustal levels. Major and trace-element difference between cores and rims in sanidine crystals represent two generations of crystal growth separated by unmixing of a carbonate melt. Trace-element differences measured by LA–ICP–MS are in accordance with silicate–carbonate unmixing. Across the core–rim boundary, we extracted gray-scale profiles from multiple accumulations of back-scattered electron images. Gray scales directly represent K/Na ratios owing to low concentrations of Ba and Sr (<?30 ppm). Diffusion gradients are modeled to solve for temperature using known pre-eruptive U–Th zircon ages (0–20 ky) of each sample (Schmitt et al., J Petrol 51:1053–1085, 2010). Estimated temperatures range from 630 °C to 670 °C. For the exsolution boundaries, a diffusive homogenization model is constrained by the solvus temperature of ~ 712^_725 °C and gives short time scales of only 15–50 days. Based on our results, we present a model for the temperature–time history of these rocks. The model also constrains the thermal variation across the cooling crystal-rich carapace of the magma reservoir over 20 ka and suggests a thermal reactivation of cumulates, the cooling carapace, and probably the entire system only a few years prior to the explosive eruption of the remaining molten core of the phonolitic magma reservoir.  相似文献   

Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 4: Plagioclase,orthopyroxene, clinopyroxene,glass geobarometer,and application to Mt. Ruapehu,New Zealand     

Lydia?J.?HarmonEmail authorView author&#;s OrcID profile  James?Cowlyn  Guilherme?A.?R.?Gualda  Mark?S.?Ghiorso 《Contributions to Mineralogy and Petrology》2018,173(1):7

A new phase equilibria geobarometer determines magmatic storage and crystallization conditions, including pressure, temperature, oxygen fugacity (\({f_{{{\text{o}}_2}}}\)), and the presence of a fluid phase for glass-bearing rocks containing the assemblage plagioclase?+?pyroxene(s). This newly developed geobarometer can better constrain crystallization conditions of shallow (<?500 MPa; <~?20 km), glass-bearing andesites to dacites. The geobarometer utilizes rhyolite-MELTS to determine crystallization conditions in natural pumice and scoria samples. The validity of the geobarometer is tested by comparing it to results from experiments. Uncertainties are assessed using Monte Carlo simulations. We apply the geobarometer to the plag?+?opx?+?cpx-bearing system of Mt. Ruapehu, in the southern Taupo Volcanic Zone, New Zealand. The samples from Mt. Ruapehu are tested from ~?5 to ~?400 MPa and from super-liquidus to 90% crystalline (~ 1200 to ~ 700 °C). Mt. Ruapehu serves as a methodological testing ground for the geobarometer, and results from our geobarometer agree with recent Mt. Ruapehu studies. Results show a distribution of crystallization pressures ranging from 50 to 150 MPa (~?2.0 to 5.9 km) for different eruptions, with modes of 110 MPa (~ 4.3 km) and 130 MPa (~ 5.1 km). These are consistent with field interpretations of different eruptive styles based on juvenile clast textures and previous knowledge of the magma plumbing system. Mt. Ruapehu magmas are fluid saturated, with \({f_{{{\text{o}}_2}}}\) of ΔQFM ~ + 1 (NNO).  相似文献   

Synthesis of monticellite–forsterite and merwinite–forsterite symplectites in the CaO–MgO–SiO<Subscript>2</Subscript> model system: influence of temperature and water content on microstructure evolution     

P.?Remmert  W.?Heinrich  B.?Wunder  L.?Morales  R.?Wirth  D.?Rhede  R.?AbartEmail authorView author&#;s OrcID profile 《Contributions to Mineralogy and Petrology》2018,173(1):5

Homogeneous single crystals of synthetic monticellite with the composition \({\text{Ca}}_{0.88}{\text{Mg}}_{1.12}{\text{SiO}}_4\) (Mtc I) were annealed in a piston-cylinder apparatus at temperatures between 1000 and \(1200\,^{\circ }\hbox {C}\), pressures of 1.0–1.4 GPa, for run durations from 10 min to 24 h and applying bulk water contents ranging from 0.0 to 0.5 wt% of the total charge. At these conditions, Mtc I breaks down to a fine-grained, symplectic intergrowth. Thereby, two types of symplectites are produced: a first symplectite type (Sy I) is represented by an aggregate of rod-shaped forsterite immersed in a matrix of monticellite with end-member composition (Mtc II), and a second symplectite type (Sy II) takes the form of a lamellar merwinite–forsterite intergrowth. Both symplectites may form simultaneously, where the formation of Sy I is favoured by the presence of water. Sy I is metastable with respect to Sy II and is successively replaced by the latter. For both symplectite types, the characteristic spacing of the symplectite phases is independent of run duration and is only weeakly influenced by the water content, but it is strongly temperature dependent. It varies from about 400 nm at \(1000\,^{\circ }\hbox {C}\) to 1200 nm at \(1100\,^{\circ }\hbox {C}\) in Sy I, and from 300 nm at \(1000\,^{\circ }\hbox {C}\) to 700 nm at \(1200\,^{\circ }\hbox {C}\) in Sy II. A thermodynamic analysis reveals that the temperature dependence of the characteristic spacing of the symplectite phases is due to a relatively high activation energy for chemical segregation by diffusion within the reaction front as compared to the activation energy for interface reactions at the reaction front. The temperature dependence of the characteristic lamellar spacing and the temperature-time dependence of overall reaction progress have potential for applications in geo-thermometry and geo-speedometry.  相似文献   

Magma evolution beneath Bequia,Lesser Antilles,deduced from petrology of lavas and plutonic xenoliths   总被引：1，自引：0，他引：1  

Michal?Camejo-HarryEmail authorView author&#;s OrcID profile  Elena?Melekhova  Jon?Blundy  William?Attridge  Richard?Robertson  Thomas?Christopher 《Contributions to Mineralogy and Petrology》2018,173(10):77

Extrusive and intrusive igneous rocks represent different parts of a magmatic system and ultimately provide complementary information about the processes operating beneath volcanoes. To shed light on such processes, we have examined and quantified the textures and mineral compositions of plutonic and cumulate xenoliths and lavas from Bequia, Lesser Antilles arc. Both suites contain assemblages of iddingsitized olivine, plagioclase, clinopyroxene and spinel with rare orthopyroxene and ilmenite. Mineral zoning is widespread, but more protracted in lavas than xenoliths. Plagioclase cores and olivine have high anorthite (An?≤?98) and low forsterite (Fo?≤?84) compositions respectively, implying crystallisation from a hydrous mafic melt that was already fractionated. Xenolith textures range from adcumulate to orthocumulate with variable mineral crystallisation sequences. Textural criteria are used to organize the xenoliths into six groups. Amphibole, notably absent from lavas, is a common feature of xenoliths, together with minor biotite and apatite. Bulk compositions of xenoliths deviate from the liquid line of descent of lavas supporting a cumulate origin with varying degrees of reactive infiltration by evolved hydrous melts, preserved as melt inclusions in xenolith crystals. Volatile saturation pressures in melt inclusions indicate cumulate crystallization over a 162–571 MPa pressure range under conditions of high dissolved water contents (up to 7.8 wt% H₂O), consistent with a variety of other thermobarometric estimates. Phase assemblages of xenoliths are consistent with published experimental data on volatile-saturated low-magnesium and high-alumina basalts and basaltic andesite from the Lesser Antilles at pressures of 200–1000 MPa, temperatures of 950–1050 °C and dissolved H₂O contents of 4–7 wt%. Once extracted from mid-crustal mushes, residual melts ascend to higher levels and undergo H₂O-saturated crystallization in shallow, pre-eruptive reservoirs to form phenocrysts and glomerocrysts. The absence of amphibole from lavas reflects instability at low pressures, whereas its abundance in xenoliths testifies to its importance in mid-crustal differentiation processes. A complex, vertically extensive (6 to at least 21 km depth) magmatic system is inferred beneath Bequia. Xenoliths represent fragments of the mush incorporated into ascending magmas. The widespread occurrence of evolved melts in the mush, but the absence of erupted evolved magmas, in contrast to islands in the northern Lesser Antilles, may reflect the relative immaturity of the Bequia magmatic system.  相似文献   

Correction to: Formation by silicate–fluoride + phosphate melt immiscibility of REE-rich globular segregations within aplite dikes     

Charles?R.?SternEmail author  Julien?M.?Allaz  Markus?B.?Raschke  G.?Lang?Farmer  M.?Alexandra?Skewes  Jeremy?T.?Ross 《Contributions to Mineralogy and Petrology》2018,173(10):79

  相似文献   

Petrology,geochemistry and geodynamic setting of Eocene-Oligocene alkaline intrusions from the Alborz-Azerbaijan magmatic belt,NW Iran     

Nasser Ashrafi  Ahmad Jahangiri  Noriko Hasebe  G. Nelson Eby 《Chemie der Erde / Geochemistry》2018,78(4):432-461

The Kaleybar, Razgah and Bozqush (KRB) intrusions were studied to better understand subduction-related Eocene-Oligocene alkaline magmatism in NW Iran. The bulk of intrusions mainly consist of Si-undersaturated rocks including foid-bearing monzonite and syenite (nepheline syenite, pseudoleucite syenite) with some foid-bearing diorite and gabbro. In addition, they are spatially associated with Si-saturated rocks ranging in composition from monzo-diorite to syeno-granite. The main mafic rock-forming minerals of the studied rocks are olivine (Fo₄₄Fa₅₆), clinopyroxene (diopside to augite), biotite (Mg-biotite through Fe-biotite), amphibole (ferro-pargasite and magnesio-hastingsite with Mg#<0.55), and garnet (Ti-andradites). Based on whole rock geochemistry, the foid-syenites and associated rocks show mildly alkaline (shoshonitic) affinity. The content of SiO₂, K₂O?+?Na₂O, and K₂O/Na₂O ratio ranges from 47.8 to 60.7?wt.%, 5.31 to 16.33?wt.%, and 0.6 to 3.2, respectively. The intrusions are commonly metaluminous, with an aluminum-saturation index (ASI) ranging from 0.66 to 1.01. Almost all the rocks display similar arc-related geochemical features characterized by the enrichment in large ion lithophile elements (LILE) and light rare earth elements (LREE) together with the depletion in high field strength elements (HFSE). The chondrite-normalized REE patterns show no to marked negative Eu anomaly (Eu/Eu*?=?0.55 to 1.12), (La/Yb)_N?=?8.16 to 31, (La/Sm)_N?=?2.80 to 10.59, and (Tb/Yb)_N?=?0.84 to 2.40. The evaluation of the REE patterns for the KRB magmas and the comparison of the trace element ratios with experimental studies indicate a chemically enriched lithospheric mantle source composed of garnet-spinel-lherzolite that have underwent a low degree of partial melting <5% to generate the KRB intrusions. Based on the present data, we infer that the mantle source was contaminated by a subduction component and the melting of the mantle lithosphere occurred by local extension in an overall convergent regime in NW Iran. The extension regime during the Eocene is proposed to be the result of the Neo-Tethys slab roll-back and the Sevan-Akera-Qaradagh (SAQ) slab break-off.  相似文献   

Sugarloaf Mountain,central Arizona,USA: A small-scale example of Miocene basalt-rhyolite magma mixing to yield andesitic magmas     

Ellen J. Craig  R.V. Fodor 《Chemie der Erde / Geochemistry》2018,78(1):116-139

Sugarloaf Mountain is a 200-m high volcanic landform in central Arizona, USA, within the transition from the southern Basin and Range to the Colorado Plateau. It is composed of Miocene alkalic basalt (47.2–49.1?wt.% SiO₂; 6.7–7.7?wt.% MgO) and overlying andesite and dacite lavas (61.4–63.9?wt.% SiO₂; 3.5–4.7?wt.% MgO). Sugarloaf Mountain therefore offers an opportunity to evaluate the origin of andesite magmas with respect to coexisting basalt. Important for evaluating Sugarloaf basalt and andesite (plus dacite) is that the andesites contain basaltic minerals olivine (cores Fo_76-86) and clinopyroxene (～Fs_9-18Wo_35-44) coexisting with Na-plagioclase (An_48-28Or_1.4–7), quartz, amphibole, and minor orthopyroxene, biotite, and sanidine. Noteworthy is that andesite mineral textures include reaction and spongy zones and embayments in and on Na-plagioclase and quartz phenocrysts, where some reacted Na-plagioclases have higher-An mantles, plus some similarly reacted and embayed olivine, clinopyroxene, and amphibole phenocrysts.Fractional crystallization of Sugarloaf basaltic magmas cannot alone yield the andesites because their ～61 to 64?wt.% SiO₂ is attended by incompatible REE and HFSE abundances lower than in the basalts (e.g., Ce 77–105 in andesites vs 114–166?ppm in basalts; Zr 149–173 vs 183–237; Nb 21–25 vs 34–42). On the other hand, andesite mineral assemblages, textures, and compositions are consistent with basaltic magmas having mixed with rhyolitic magmas, provided the rhyolite(s) had relatively low REE and HFSE abundances. Linear binary mixing calculations yield good first approximation results for producing andesitic compositions from Sugarloaf basalt compositions and a central Arizona low-REE, low-HFSE rhyolite. For example, mixing proportions 52:48 of Sugarloaf basalt and low incompatible-element rhyolite yields a hybrid composition that matches Sugarloaf andesite well ? although we do not claim to have exact endmembers, but rather, viable proxies. Additionally, the observed mineral textures are all consistent with hot basalt magma mixing into rhyolite magma. Compositional differences among the phenocrysts of Na-plagioclase, clinopyroxene, and amphibole in the andesites suggest several mixing events, and amphibole thermobarometry calculates depths corresponding to 8–16?km and 850° to 980?°C. The amphibole P-T observed for a rather tight compositional range of andesite compositions is consistent with the gathering of several different basalt-rhyolite hybrids into a homogenizing ‘collection' zone prior to eruptions. We interpret Sugarloaf Mountain to represent basalt-rhyolite mixings on a relatively small scale as part of the large scale Miocene (～20 to 15 Ma) magmatism of central Arizona. A particular qualification for this example of hybridization, however, is that the rhyolite endmember have relatively low REE and HFSE abundances.  相似文献   

Calibration of AGRS System Using Transportable Pads in India: An Application to AGRS Data of Aravalli Basin,Banswada Block,South Rajasthan     

M. S. Ramayya  A. K. Chaturvedi  P. S. Parihar  P. K. Sharma  D. U. Jiwane  P. K. Srivastava  T. C. Sunil 《Journal of the Geological Society of India》2018,91(5):535-540

Calibration of airborne gamma ray spectrometric system (AGRS) over standard radioactive sources of known elemental abundances is essential before carrying out airborne surveys. In India, fixed calibration pads were constructed in 1985. Since then calibration of AGRS system was carried out over the fixed pads. However the fixed pads are expensive to build and maintain. Also the large pads are subject to variations in radiation output due to variable moisture content and radon loss. Alternate approach is to construct transportable calibration pads which are discussed in this paper.Atomic Minerals Directorate for Exploration & Research (AMD) under Department of Atomic Energy has recently constructed five transportable calibration pads. Three pads i.e. K, U and Th have been spiked with the respective radioelements while keeping the minor radioelements to the least in order to obtain pure spectra. A composite pad has been constructed which contains all the three radioelements. This helps in cross verifying the obtained calibration results. A background pad has also been constructed which is helpful to obtain the background values during calibration.Analysis of the data acquired over the transportable pads with airborne gamma ray spectrometer (16.8 ltr) has been carried out and presented in this paper. A comparison with the data acquired over the fixed calibration pads is also included. There is a good agreement of results which suggests the use of transportable pads in future.  相似文献   

Influence of Geo-environmental and Chemical Factors on Thermotolerant Coliforms and <Emphasis Type="Italic">E.coli</Emphasis> in the Groundwater of Central Kerala     

M. S. Sreekala  Sarah John Sareen  Sivalingam Rajathi 《Journal of the Geological Society of India》2018,91(5):621-626

Geo-environmental studies in parts of Ernakulam district (Kerala, India) were carried out. The study area comprises of sedimentary (Limestone, sandstone, Clay and Lignite) and crystalline (Charnockite and gneisses) rocks. The sedimentary terrain is characterized by confined and unconfined aquifers. In hard crystalline formations groundwater occurs under phreatic conditions in the shallow weathered portions and under semi confined to confined conditions in the deep-seated fractures. The study area is demarcated into five areas based on soil types. Climate is hot humid to hot summer with heavily raining monsoon. Two major rivers Periyar and Muvattupuzha drain through the area. Agricultural and industrial activities are prevalent in Ernakulam district. The major cause of pollution in the study area is due to the presence of coliforms. Detailed investigations carried out to identify the coliforms indicated spatial and seasonal changes in the distribution pattern. Monsoon and post monsoon showed significantly high total coliforms compared to pre-monsoon. Thermo-tolerant coliforms is high during monsoon season. This seasonal change could be due to the effect of rainfall, overland flow, nutrient load and temperature change. Wide variations in the coliform counts are observed in wells situated near rivers, canals, paddy fields and in water bodies lying close to pilgrimage center, fertilizer industry, and public places. It is noticed that the chemical characteristics of the groundwater influence the coliform survival. pH, nitrite, bicarbonate, hardness, and alkalinity play a significant role in controlling coliform count. At the outset, the study highlighted the impact of anthropogenic activities on ground water in a coastal district of Kerala state.  相似文献   

Identifying Water Storage Variation in Krishna Basin,India from <Emphasis Type="Italic">in situ</Emphasis> and Satellite based Hydrological Data     

H. Munagapati  R. Yadav  V. M. Tiwari 《Journal of the Geological Society of India》2018,92(5):607-615

Terrestrial water storage (TWS), a sum total of water stored on or beneath the earth’s surface, transits in response to hydroclimatic processes such as precipitation, evapo-transpiration, runoff etc. and serves an indicator of hydrological condition of a region. We analyse spatio-temporal variance of water storage in Krishna Basin, India, derived from in-situ groundwater data and Gravity Recovery and Climate Experiment (GRACE) satellite data in order to determine physical causes of variations, and compare the variance with climatic factors such as Cumulative Rainfall Departure (CRD) and drought index i.e. Standardized Precipitation Index (SPI). GRACE satellite based TWS is found to reflect insitu groundwater changes and also shows a relationship with drought patterns as indicated by a good correlation with SPI. The largest part of TWS represents seasonal flux, and at an interannual scale, TWS depicts spatio-temporal variability in response to drought index viz. SPI. We infer that the groundwater storage derived from GRACE time-variable gravity solutions can be utilised to complement in-situ observations at basin scale and it reflects climatic forcing quite well.  相似文献